Honey

on Tuesday, March 31, 2009

From Wikipedia, the free encyclopedia

Honey is a sweet fluid produced by honey bees (and some other species), and derived from the nectar of flowers. According to the United States National Honey Board and various international food regulations, "honey stipulates a pure product that does not allow for the addition of any other substance…this includes, but is not limited to, water or other sweeteners". This article refers exclusively to the honey produced by honey bees (the genus Apis); honey produced by other bees or other insects has very different properties.

Honey gets its sweetness from the monosaccharides fructose and glucose and has approximately the same relative sweetness as that of granulated sugar (97% of the sweetness of sucrose, a disaccharide). Honey has attractive chemical properties for baking, and a distinctive flavor which leads some people to prefer it over sugar and other sweeteners.

Most micro-organisms do not grow in honey because of its low water activity of 0.6. However, honey frequently contains dormant endospores of the bacteriumClostridium botulinum, which can be dangerous to infants as the endospores can transform into toxin-producing bacteria in the infant's immature intestinal tract, leading to illness and even death (see Potential health hazards below).

The study of pollens and spores in raw honey (melissopalynology) can determine floral sources of honey. Because bees carry an electrostatic charge, and can attract other particles, the same techniques of melissopalynology can be used in area environmental studies of radioactive particles, dust, or particulate pollution.

A main effect of bees collecting nectar to make honey is pollination, which is crucial for flowering plants.

Beekeepers encourage overproduction of honey within the hive so that the excess can be taken without endangering the bees. When sources of food for the bees are short, beekeepers may have to give the bees supplementary nutrition. Supplementary nutrition usually comes in the form of sugar (sucrose) mixed with water at proper ratios.

Formation

Honey is created by bees as a food source. In cold weather or when food sources are scarce, bees use their stored honey as their source of energy. By contriving for bee swarms to nest in artificial hives, people have been able to semi-domesticate the insects, and harvest excess honey. In the hive there are three types of bee: a single female queen bee, a seasonally variable number of male drone bees to fertilize new queens, and some 20,000 to 40,000 female worker bees. The worker bees raise larvae and collect the nectar that will become honey in the hive. Leaving the hive, they collect sugar-rich flower nectar and return. In the process, they release Nasonov pheromones. These pheromones lead other bees to rich nectar sites by "smell". Honeybees also release Nasonov pheromones at the entrance to the hive, which enables returning bees to return to the proper hive.

In the hive the bees use their "honey stomachs" to ingest and regurgitate the nectar a number of times until it is partially digested. The bees work together as a group with the regurgitation and digestion until the product reaches a desired quality. It is then stored in honeycomb cells. After the final regurgitation, the honeycomb is left unsealed. However, the nectar is still high in both water content and natural yeasts which, unchecked, would cause the sugars in the nectar to ferment. The process continues as bees inside the hive fan their wings, creating a strong draft across the honeycomb which enhances evaporation of much of the water from the nectar. This reduction in water content raises the sugar concentration and prevents fermentation. Ripe honey, as removed from the hive by a beekeeper, has a long shelf life and will not ferment if properly sealed.


Nutrition

Honey
Nutritional value per 100 g (3.5 oz)

Energy 300 kcal 1270 kJ

Carbohydrates

82.4 g

- Sugars 82.12 g

- Dietary fiber 0.2 g

Fat

0 g

Protein

0.3 g

Water

17.10 g

Riboflavin (Vit. B2) 0.038 mg

3%

Niacin (Vit. B3) 0.121 mg

1%

Pantothenic acid (B5) 0.068 mg

1%

Vitamin B6 0.024 mg

2%

Folate (Vit. B9) 2 μg

1%

Vitamin C 0.5 mg

1%

Calcium 6 mg

1%

Iron 0.42 mg

3%

Magnesium 2 mg

1%

Phosphorus 4 mg

1%

Potassium 52 mg

1%

Sodium 4 mg

0%

Zinc 0.22 mg

2%

Shown is for 100 g, roughly 5 tbsp.
Percentages are relative to US
recommendations for adults.

Source: USDA Nutrient database


Honey is a mixture of sugars and other compounds. With respect to carbohydrates, honey is mainly fructose (about 38.5%) and glucose (about 31.0%), making it similar to the synthetically produced inverted sugar syrup which is approximately 48% fructose, 47% glucose, and 5% sucrose. Honey's remaining carbohydrates include maltose, sucrose, and other complex carbohydrates. Honey contains trace amounts of several vitamins and minerals. As with all nutritive sweeteners, honey is mostly sugars and is not a significant source of vitamins or minerals. Honey also contains tiny amounts of several compounds thought to function as antioxidants, including chrysin, pinobanksin, vitamin C, catalase, and pinocembrin. The specific composition of any batch of honey will depend largely on the mix of flowers available to the bees that produced the honey.

Typical honey analysis

  • Fructose: 38.5%
  • Glucose: 31.0%
  • Sucrose: 1.0%
  • Water: 17.0%
  • Other sugars: 9.0% (maltose, melezitose)
  • Ash: 0.17%
  • Other: 3.38%

Honey has a density of about 1.36 kilograms per liter (36% denser than water).

Isotope ratio mass spectrometry can be used to detect addition of corn syrup or sugar cane sugars by the carbon isotopic signature. Addition of sugars originated from corn or sugar cane (C4 plants, unlike the plants used by bees which are predominantly C3 plants) skews the isotopic ratio of sugars present in honey, but does not influence the isotopic ratio of proteins; in an unadulterated honey the carbon isotopic ratios of sugars and proteins should match. As low as 7% level of addition can be detected.

Classification by floral source

Generally, honey is classified by the floral source of the nectar from which it was made. Honeys can be from specific types of flower nectars, from indeterminate origin, or can be blended after collection.

Blended
Most commercially available honey is blended, meaning that it is a mixture of two or more honeys differing in floral source, color, flavor, density or geographic origin.

Polyfloral
Polyfloral honey, also known as wildflower honey, is derived from the nectar of many types of flowers. The taste may vary from year to year, and the aroma and the flavour can be more or less intense, depending on which bloomings are prevalent.

Monofloral Monofloral honey is made primarily from the nectar of one type of flower. Different monofloral honeys have a distinctive flavor and colour because of differences between their principal nectar sources. In order to produce monofloral honey beekeepers keep beehives in an area where the bees have access to only one type of flower. In practice, because of the difficulties in containing bees, a small proportion of any honey will be from additional nectar from other flower types. Typical examples of North American monofloral honeys are clover, orange blossom, sage, eucalyptus, tupelo, manuka, buckwheat, and sourwood. Some typical European examples include thyme, thistle, heather, acacia, dandelion, sunflower, honeysuckle, and varieties from lime and chestnut trees.

Honeydew honey
Instead of taking nectar, bees can take honeydew, the sweet secretions of aphids or other plant sap-sucking insects. Honeydew honey is very dark brown in colour, with a rich fragrance of stewed fruit or fig jam and is not as sweet as nectar honeys. Germany's Black Forest is a well known source of honeydew-based honeys, as well as some regions in Bulgaria. Honeydew honey is popular in some areas, but in other areas beekeepers have difficulty selling the stronger flavored product.

The production of Honeydew honey has some complications and dangers. The honey has a much larger proportion of indigestibles than light floral honeys, which can cause dysentery to the bees, resulting in the death of colonies in areas with cold winters. Good beekeeping management requires the removal of honeydew prior to winter in colder areas. Bees collecting this resource also have to be fed protein supplements, as honeydew lacks the protein-rich pollen accompaniment gathered from flowers.

Packaging and processing

Honey comb
Generally, honey is bottled in its familiar liquid form. However, honey is sold in other forms, and can be subjected to a variety of processing methods.


Comb honey
• Comb honey is honey meant to be consumed still in the honeybees' wax comb. Comb honey traditionally is collected by using standard wooden frames in honey supers. The frames are collected and the comb cut out in chunks before packaging. As an alternative to this labor intensive method, plastic rings or cartridges can be used that do not require manual cutting of the comb, and speed packaging. Comb honey harvested in the traditional manner is also referred to as "Cut-Comb honey"
• Chunk honey is honey packed in widemouth containers consisting of one or more pieces of comb honey immersed in extracted liquid honey.


Organic

• Certified Organic Honey is honey or honey combs produced, processed, and packaged in accordance with national regulations, and certified as such by some government body or an independent organic farming certification organization. In the United Kingdom, the standard covers not only the origin of bees, but also the siting of the apiaries. These must be on land that is certified as organic, and within a radius of 4 miles from the apiary site, nectar and pollen sources must consist essentially of organic crops or uncultivated areas.

According to TheOrganicReport.com, organic honey is quite scarce to find because most beekeepers "routinely use sulfa compounds and antibiotics to control bee diseases, carbolic acid to remove honey from the hive, and calcium cyanide to kill colonies before extracting the honey, not to mention that conventional honeybees gather nectar from plants that have been sprayed with pesticides."


Varieties of processing


Crystallized honey is honey in which some of the glucose content has spontaneously crystallized from solution as the monohydrate. Also called "granulated honey."

Pasteurized honey is honey that has been heated in a pasteurization process.Pasteurization in honey reduces the moisture level, destroys yeast cells, and liquefies crystals in the honey. While this process sterilizes the honey and improves shelf-life, it has some disadvantages. Excessive heat-exposure also results in product deterioration, as it increases the level of hydroxymethylfurfural (HMF) and reduces enzyme (e.g. diastase) activity. The heat also affects appearance, taste, and fragrance. Heat processing can also darken the natural honey color (browning).

Raw honey is honey as it exists in the beehive or as obtained by extraction, settling or straining without adding heat above 120 °F. Raw honey contains some pollen and may contain small particles of wax. Local raw honey is sought after by allergy sufferers as the pollen impurities are thought to lessen the sensitivity to hay fever (see Medical Applications below). • Strained honey is honey which has been passed through a mesh material to remove particulate material (pieces of wax, propolis, other defects) without removing pollen, minerals or valuable enzymes.

Ultrafiltered honey is honey processed by very fine filtration under high pressure to remove all extraneous solids and pollen grains. The process typically heats honey to 150–170 °F to more easily pass through the fine filter. Ultrafiltered honey is very clear and has a longer shelf life, because it crystallizes more slowly because of the high temperatures breaking down any sugar seed crystals, making it preferred by the supermarket trade. The heating process degrades certain qualities of the honey similar to the aforementioned pasteurization process.

Ultrasonicated honey is honey that has been processed by ultrasonication, a non-thermal processing alternative for honey. When honey is exposed to ultrasonication, most of the yeast cells are destroyed. Yeast cells that survive sonication generally lose their ability to grow. This reduces the rate of honey fermentation substantially. Ultrasonication also eliminates existing crystals and inhibits further crystallization in honey. Ultrasonically aided liquefaction can work at substantially lower temperatures of approx. 35 °C and can reduce liquefaction time to less than 30 seconds.

Whipped honey, also called creamed honey, spun honey, churned honey, candied honey, and honey fondant, is honey that has been processed to control crystallization. Whipped honey contains a large number of small crystals in the honey. The small crystals prevent the formation of larger crystals that can occur in unprocessed honey. The processing also produces a honey with a smooth spreadable consistency.